RB-09-04 PNE Readme File Ship: NOAA research vessel Ronald H. Brown Cruise Start: Bridgetown, Barbados, July 11, 2009 Cruise End: San Juan, Puerto Rico, Aug. 4, 2009 Chief Scientists: Rick Lumpkin System Operator: Jonathan Shannahoff Method: The system was built by General Oceanics (GO) and is described in Pierrot, et al. (2009). The three standard gases come from CMDL in Boulder and are directly traceable to the WMO scale. Sampling Cycle: The system runs on an cycle during which 4 standard gases, 5 air samples from the bow tower and 50 surface water samples (from the equilibrator head space) are analyzed on the following schedule: 1. Zero and span of Licor 2. Four standard gases 3. Five air samples 4. Fifty equilibrator headspace gas samples 5. Repeat steps 2 - 4 nine more times 6. Restart from step 1 Standards: CA6709: 284.75 ppm, CA2813: 363.24 ppm, CA9721: 432.57 ppm, CA7931: 545.88 ppm. Units: All xCO2 values are reported in parts per million (ppm) and fCO2 values are reported in microatmospheres (uatm) assuming 100 % humidity at the equilibrator temperature. Notes: 1. Any values outside the range of the standards (284.75 to 545.88 ppm) have been flagged as 3 and should be considered approximate (within 5 ppm). While individual data points above 545 or below 285 may not be accurate, the general trends should be indicative of the seawater chemistry. 2. Salinity readings from the ship's TSG were bad. Readings from the Seabird Micro TSG connected to the analytical system were used instead. 3. An offset of 3.50 minutes was applied to SST data from the ship's computer system. 4. There were 2 prolonged data interruptions. The first occurred on July 18 at 05:07 and lasted until July 19 at 20:30. The second started on July 29 at 03:03 and ended on August 1 at 16:52. For questions or comments contact: Bob Castle 4301 Rickenbacker Causeway Miami, FL 33149 305-361-4418 robert.castle@noaa.gov Pierrot, D., C. Neil, K. Sullivan, R. Castle, R. Wanninkhof, H. Lueger, T. Johannson, A. Olsen, R. A. Feely, and C. E. Cosca (2009), Recommendations for autonomous underway pCO2 measuring systems and data reduction routines, Deep-Sea Res II, 56, 512-522.